NiO 촉매의 분산성 및 안정성 향상을 위하여 FeCrAl 합금 폼 위에 성장된 Al2O3 Inter-Layer 효과

서지정보

ㆍ발행기관 : 한국재료학회 ㆍ수록지정보 : 한국재료학회지 / 25권 / 8호
ㆍ저자명 : 이유진, 구본율, 백성호, 박만호, 안효진

목차

1. 서 론
2. 실험 방법
3. 결과 및 고찰
4. 결 론
Acknowledgement
References

영어 초록

NiO catalysts/Al2O3/FeCrAl alloy foam for hydrogen production was prepared using atomic layer deposition (ALD)and subsequent dip-coating methods. FeCrAl alloy foam and Al2O3 inter-layer were used as catalyst supports. To improve thedispersion and stability of NiO catalysts, an Al2O3 inter-layer was introduced and their thickness was systematically controlledto 0, 20, 50 and 80nm using an ALD technique. The structural, chemical bonding and morphological properties (includingdispersion) of the NiO catalysts/Al2O3/FeCrAl alloy foam were characterized by X-ray diffraction, X-ray photoelectronspectroscopy, field-emission scanning electron microscopy and scanning electron microscopy-energy dispersive spectroscopy. Inparticular, to evaluate the stability of the NiO catalysts grown on Al2O3/FeCrAl alloy foam, chronoamperometry tests wereperformed and then the ingredient amounts of electrolytes were analyzed via inductively coupled plasma spectrometer. We foundthat the introduction of Al2O3 inter-layer improved the dispersion and stability of the NiO catalysts on the supports. Thus, whenan Al2O3 inter-layer with a 80nm thickness was grown between the FeCrAl alloy foam and the NiO catalysts, it indicatedimproved dispersion and stability of the NiO catalysts compared to the other samples. The performance improvement can beexplained by optimum thickness of Al2O3 inter-layer resulting from the role of a passivation layer.

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