Study of the preparation and electrochemical performance of porous carbon derived from hypercrosslinked polymers
* 본 문서는 배포용으로 복사 및 편집이 불가합니다.
서지정보
ㆍ발행기관 : 한국탄소학회
ㆍ수록지정보 : Carbon letters / 32권 / 3호
ㆍ저자명 : Lili Wu, Pitao Wang, Xinguo Chen, Jianqiang Zhang, Heming Luo
ㆍ저자명 : Lili Wu, Pitao Wang, Xinguo Chen, Jianqiang Zhang, Heming Luo
목차
Abstract1 Introduction
2 Experimental method
2.1 Preparation of carbon precursor
2.2 Preparation of porous carbon materials
2.3 Structural performance characterization
2.4 Preparation of the working electrode
2.5 Electrochemical performance test
3 Results and discussion
3.1 Phase analysis
3.2 Microstructure
3.3 Surface composition and element analysis
3.4 Electrochemical performance analysis
4 Conclusion
Acknowledgements
References
영어 초록
Hypercrosslinked polymers HCPs have been widely used as precursors to prepare porous carbon materials because of their highly ordered porous structure and large specific surface area. In this paper, we used a solvothermal method to prepare a hypercrosslinked polymer, and the HCPC-700-A was prepared using an activation method with the hypercrosslinked polymer as the precursor. The effects of different carbon–alkali ratios on the microstructure, composition and electrochemical properties of porous carbon HCP were studied. The results show that the surface of porous carbon HCPC-700-A presents a relatively regular geometric shape, and a large number of pore structures are mainly micro- and mesopores. The specific surface area is 2074.53 m2 g− 1, and the average pore size is between 1.29 and 1.93 nm. Porous carbon HCPC-700-1:2 has excellent electrochemical performance in 1 M H2SO4, and the specific capacitance is up to 464.4 F g− 1 at a current density of 1 A g− 1. The specific capacitance decay rate is 29.72% when the current density is increased from 1 A g− 1 to 8 A g− 1. After 5000 cycles, the capacitance retention rate is 91.16% at a current density of 2 A g− 1, showing excellent electrochemical performance, good cycle stability and perfect energy storage performance. This research provides new experimental ideas for HCPs in the electrochemical energy storage field.참고 자료
없음"Carbon letters"의 다른 논문
- Thermal and mechanical properties of diamond/SiC substr..9페이지
- Activated carbon fibers derived from natural cattail fi..9페이지
- Modified organic reagent for deeply purifying crude TiC..13페이지
- Production of Fe3C/ N‑doped carbon hybrid and its elect..8페이지
- UiO‑66‑derived porous‑carbon adsorbents: synthesis, cha..10페이지
- Study on fractal model of activated carbon for pore for..11페이지
- In situ formed nano‑Ni catalytic effect on graphitizati..14페이지
- Experimental analysis and optimization on machining of ..19페이지
- Ammonia etched petroleum pitch‑based porous carbon as e..8페이지
- Effects of chemical composition of carbonaceous powder ..9페이지